matt brown wrote: ↑Thu Mar 17, 2022 12:51 am
Tom Booth wrote: ↑Wed Mar 16, 2022 9:09 am
I asked simply, show me some record of any actual experimental verification, or any empirical evidence whatsoever that validates or ever in the history of the world, actually demonstrated the accuracy and validity of the Carnot efficiency equation
That request should not be so difficult to fulfill if the equation had any real validity. All either of you have shown are theoretical "idealizations" based on NOTHING but speculation.
Tom - all the Carnot buzz (and a lot of thermo) is derived from PV=nRT which is the basis of the kinetic theory. A bunch of guys spent a lot of time arriving at this famous equation and no one has disproved it. It goes back to Herapath and Waterson where PV/T was a well 'observed' constant.
Thermal pic shows bottom plate hot with top plate nearly ambient. So what ?..it's the heat RATE in and out of gas that matters, not temperature of each plate, tho there must be some dT. It appears top plate is insulated from main unit.
Are you suggesting that a thermal scan like this is telling us that any/all heat going into gas is transformed into work since the 'cold' plate remains ambient, whereby Qout=0 ???
Simply put, in the process of researching the question; how does a Stirling engine actually work, from an engineering point of view, that is, as a life long engine mechanic/repair man, I wanted to build and use one, I came across a number of
conflicting points of view, theories, explainations, and alleged "Laws".
Historically, as far as I could tell, some of these conflicts, or differences of opinion had never been fully resolved, including the actual nature of "heat" itself.
High on the list of conflicting theories is the "Carnot efficiency equation" which carries with it a number of basic assumptions
In the case of the thermal image in question above, 80% (or more) of the heat entering the engine through the bottom plate should be (according to E=1-Qh/Qc) passing through to the top plate each cycle. A mere 20% (or less) being converted to work.
Taking this image, along with several experiments, temperature readings (that show no rise in temperature at the point of "heat rejection" at the "sink"), running engines on ice, (that re-freezes rather than melting), engine performance improving when heat flow out of the engine is blocked, etc.
All taken together, the indication is that the Carnot efficiency equation, or how it is being interpreted, is invalid.
Further, there is no historical empirical support for it. PV=nRT is not E=1-Qh/Qc
Neither of those equations directly address the conversation of heat into work.
There is, as far as I can find, no scientific basis for assuming that the ratio between the high and low temperatures has anything to do with engine efficiency, or how effective the engine is at converting the available heat into work.
Carnot himself, it appears, rejected this formula, though this was unknown until many years later when his personal journals were published.
I've already pointed out, it is accepted that 100% conversion of heat into work is possible, linearly.
That is, in expansion work, to drive a piston out 100% conversion of heat into work is possible.
The issue is supposed to be associated with completing the cycle. Supposedly the piston has to be pushed back to its starting position and this takes work and supposedly to get the gas to contract after expanding heat has to be removed.
These assumptions also appear to be inaccurate in actual practice.
All in all, the idea that efficiency (% utilization of available heat) is strictly limited by the ∆T ratio appears to have no factual basis. Observably, experimentally, measurably, it doesn't hold up.
To assert something is true on the basis that "it has never been proven wrong" is not science. That would be called faith.
E=1-Qh/Qc (or how it is being interpreted) is more a kind of religious conviction than a well established scientific fact.
The temperature difference is just the temperature difference. It has not been proven to be a limiting factor on the utilization of the available heat.