MikeB wrote: ↑Fri Oct 15, 2021 8:46 am
Tom, I see you mention "molecular attraction" again - I'm not aware that any common gas has this property; indeed I was under the impression that a truly un-constrained gas would expand to fill whatever container it is in, regardless of temperature and pressure. Maybe I'm misunderstanding a concept that you are getting at, but surely a gas will only contract if there is an external pressure acting on it?
A so-called "Ideal Gas" is not supposed to have molecular forces. Real gases however do, but I'm not at all certain on what scale, or if it comes into play.
I'm relating it to the rubber band analogy, which may be entirely inappropriate.
Stretching a rubber band generates heat by "doing work" on the rubber to stretch it out. Released, the rubber band "does work" and gets cold, due to using up some "internal energy" the rubber "wants" to pull itself back into the relaxed, unexpanded state it was in before it was stretched.
It is often stated that air is elastic, or has elastic like properties, more or less opposite to a rubber band, as stated in the above video in a non technical way.
So gas cools when it expands doing work and heats up when compressed, work being done on it.
At a certain point, when cooled sufficiently, the molecular attraction between gas molecules dominates and a change of state occurs. The gas condenses into a liquid. At what point is different for different gases.
Air is a mixture of gases, as well as water vapor.
You might say that "intuitively", I kind of suspect that the gas in a Stirling engine, expanding and doing work, experiences a rather sharp, sudden cooling that stops the piston in its tracks, causing it to reverse direction, at least in part, due to a sudden "condensation" of some constituent in the air/gas.
A sudden change in air pressure will condense water out of the air, if nothing else.
Just as an example of what I mean. A very common physics experiment is to put a little bit of water in a metal can, bring it to a boil, then put the lid on when the can fills with water vapor.
Remove the heat so the vapor cools and condenses back into a liquid. The can collapses.
Now, it if often stated that it is the outside atmospheric pressure that caused the can to collapse.
But, thinking about it, what caused there to be a vacuum inside the can in the first place? The vacuum inside the can was created, first, by the molecular attraction between the water molecules, right?
So when a gas in a Stirling engine expands, does work and cools, SOMETHING happens to reduce the pressure inside the engine that results in the outside atmospheric pressure dominating.
What causes the internal pressure to suddenly drop below the external pressure? The gas cools.
But cold gas can still be under high pressure. What reduces the pressure? What else can it be but molecular attraction? This seems to follow logically. Maybe.
Somehow at least in the.case of water vapor condensing, I tend to think that the violent implosion of the can is due to something more than simply outside atmospheric pressure. It is also the condensation of the water vapor which is a result of molecular attraction that creates the vacuum.
So, back to the rubber band, it cools as it does work as it contracts, NOT due to external pressure.
Is it not conceivable that a cooling "condensing" gas in an engine FIRST undergoes molecular attraction as it cools, which results in the vacuum condition inside the engine that only AFTERWARD results in the pre-existing outside atmospheric pressure dominating?
https://youtu.be/p3b9pK-O6cE
I guess it is more like a support being taken out from under something. The removed support does not actually do any "work" to "pull" something down after or as the support is being removed.
So the cooling contracting gas does not "pull" the piston inward, rather it just no longer serves as a support for the piston which allows the outside pressure to push the piston in.
At some point, before the end of the compression stroke, the in-rushing atmosphere/piston does some work on the internal gas.
I think I've worked out the answer to my own question.