Fool wrote: ↑Wed Jun 12, 2024 9:56 am
In fact I'll do it again.
Qh heat added from Tc to get to Th.
Uh total energy contained in the gas at Th
Uc total energy contained in the gas at Tc
Qh=Uh-Uc
100=400-300
Heat equals the change in internal energy.
Starting point one:
Uc=MCvTc
300=MCv300
Maximum point two:
Uh=MCvTh
400=MCv400
MCv= Mass times constant chosen so it is one.
If an engine forward stroke starts while containing Uh 400 Joules, the most work it can produce is 400 J. This will be when it gets to absolute zero Kelvin. We want a maximum. The piston returns to the starting point costing zero back work, because it is at zero Kelvin. The buffer pressure has added a total of nothing because the same pressure opposed the forward stroke, as helped the back stroke. P∆V work, out forward stroke, in backward stroke, same P∆V
Now, back at the starting volume and zero K, 300 J must be added to complete the cycle. That 300 Joules must come from the forward work. Why? Because we are only adding 100 J. 300 J more must come from somewhere to get to the 400 J second position and 300 J starting first position. Forward work is the only energy available.
If the atmosphere were expected to add the Joules, it will do it at Tc for the entire return stroke and 300 J of work will be needed to compress the gas.
If the buffer pressure force compresses it, 300 J Uc will be rejected as energy of compression to the cold sink as heat, to keep the reverse work at a minimum.
So, it starts with Uh and returns the amount Uc to complete the cycle. The maximum efficiency to start at Uc, add Qh, expand all the way to zero borrowing from the Uc energy, return the extra gained by over expanding to become a cold hole by adding back the borrowed heat Uc, during the return stroke, to complete the cycle is:
n=(Uh-Uc)/Uh
Maximum efficiency after all ideas have been tried.
Substituting in the temperature energy formulas Ut=MCvTh:
n=(MCvTh-MCvTc)/(MCvTh)
Canceling MCv top and bottom.
n=(Th-Tc)/Th
This raises the question, Why is Qc subject to the same efficiency as Uc? It's the same engine operating from the same temperatures. It should get the same efficiency even if we calculated all the work Uc could supply on the single forward stroke. Again it is the return stroke that gets it.
If it is obfuscated with buffer pressure, then the forward stroke gets it. There is no efficiency win from applying buffer pressure to a full cycle. It cancels too. Or as Matt says, there's no free lunch from buffer pressure in regard to efficiency.
This is Proof that mathematically shows the cancelations, and scientifically describes why it is an absolute maximum when operating in a full cycle from two limiting temperatures.