Again, as usual, you take my musings out of context.Fool wrote: ↑Mon Sep 30, 2024 3:31 am I think you need to learn more about "molecular change", molecular switch", "molecular bonding", and "evolution.
Helium has no/zero molecular change, or switch, over a range of larger than, 50 Kelvin and below, to and above, 1000 Kelvin. A Stirling engine will run just fine, well within that range. Proving no molecular change is needed for operation of a Stirling engine.
I said "
molecular bonding"such things as...
I think hydrogen bonding may very well enter into the picture where atmospheric humidity is involved, and in "wet" thermoacoustic type engines. The steam in a 55 gallon drum experiment, but also "such things" might, or would likely mostly include molecular attraction and repulsion of any or all types generally.
Sure, heating and cooling causes expansion and/or contraction.
Classical thermodynamics does not generally account for molecular attraction and repulsion generally, and is particularly lost when it comes to something involving expansion that results from cooling, or "work" force that might result from molecular attraction.
You, Matt and others often assert that there is no molecular attraction in any gas or in a hot air engine, but physics and chemistry generally say otherwise. "Of course gas molecules have attraction and repulsion" as I recall a statement from one video I posted, loosely paraphrased.
Anyway, the cause behind the cause.
So called "heat" is considered THE cause, the primary or even the only cause or source of power generation, ultimately, for a "heat" engine.
But there is basically no such thing as "heat" but merely motion.
What actually causes motion? Certainly not "heat" which doesn't actually exist. What does exist? The particles and their various interactions; attraction, repulsion, bonding and so forth
In this video there is a lot of talk about attraction, "mutual attraction" etc.
https://youtu.be/0kfcigx-AUc
The video is about "bonding" but before and after bonding there is attraction and repulsion.
Attraction and repulsion between particles is, presumably, REAL. Heat is not anything. Or what exactly does it consist of?
Conventional or classical thermodynamics is obsolete and mostly just keeps its head in the sand ignoring reality and modern advances in understanding.
It's a "science" of something that doesn't actually exist or even consistently behave as supposed.
Example: adding heat does not always cause expansion. Sometimes cooling does, and sometimes "contraction" can do substantial "work". Did Carnot, Kelvin or any of the other "Fathers of thermodynamics" consider or factor in this observable fact?
Here at the start of this video, removing heat by cooling is demonstrated to sheer a large cast iron pin.
https://youtu.be/EkQ2886Sxpg
Is that, or does that in some way involve the conversion of "heat" into "work"?
True, initially heat was added, but I think the same effect would result from cooling from ambient alone, if the cooling were deeper, using dry ice or liquid nitrogen or something.
The essential thing IMO is that the objects, whatever they may be exist in a state of equilibrium with the environment and with each other. Heating and cooling disturb that equilibrium. "Work" then, can be extracted as there is a natural return to a state of equilibrium after a disturbance.
Carnot called this a return in equilibrium to the "Caloric" or a "restoration" or some such phraseology I don't recall exactly.
The quote seems a bit garbled, taken 2nd hand from here:"Getting movement in steam engines is always accompanied by one circumstance to which we should pay attention. This circumstance is the restoration of caloric balance, that is, the transition the heat from the body with a higher temperature, to another, where it is below .. . The appearance of the driving force in steam engines is going not due to loss of the heat, but due to transition from hot to cold. There is a restoration of its balance - balance, which was initiated some reason, the chemical action as burning, or something else. We see that this principle applies to all vehicles powered by heat.
According to this principle, it is not enough to create the heat to cause a driving force: you still get the cold; without it the heat would be unnecessary. "
https://kpi.ua/en/karno
But of course, there is no such thing as "Caloric" and therefore no such thing as the "restoration of Caloric balance". But there is the balance of molecular attraction and repulsion, which for some reason is often largely ignored, or denied.
Gas or air molecules in the atmosphere and/or within and outside a hot air engine are naturally in a state of equilibrium until disturbed by heating OR cooling.
So expansion and/or CONTRACTION of a gas will produce a force that can power an engine as nature goes about restoring the equilibrium.
In other words, a Stirling engine is an oscillator, as previously suggested.