Fool wrote: ↑Fri Sep 27, 2024 11:37 am
Evaporation takes energy away in the form of mass transfer. It is an outflow of energy from the system. The system gets colder because it is warmer than the evaporation temperature. Phase change temperature constant only happens at freezing or boiling, this happens between those temperatures. The heat in the warmer bird-head-gas flows outwards to the colder bird-head-skin/felt. Heat transfers out of the system. Second law proof, yet again.
The "system" includes the surrounding air, and the evaporating water, as well as heat from the sun, and as you pointed out earlier, the cold of outer space.
So now by limiting "the system" to what happens within the interior of the glass bulb you are contradicting yourself. You just arbitrarily move the system boundary to arrive at an apparent confirmation of Carnot, but without what happens outside the bulb, you don't have a working engine, you have a paperweight
Eventually, the escaping water vapor might re-condense somewhere releasing the "heat" it "removed", but that is not a given and such remote condensation will have no effect on the operation of the bird.
The "system", logically, should at least include all those things immediately necessary for the operation of the engine cycle which would include the evaporation process.
An "outflow of energy" by evaporation is not the same as "heat removal" or "heat rejection".
But more pointedly, the similar energy conversion in a Stirling engine that results in heat being transformed into the kinetic motion of the engine, accompanied by a drop in temperature, is not "heat rejection " or "heat removal".
All quibbling over what constitutes "the system" or semantics generally, experimentally there is what you call a "temperature anomaly"; no detectable temperature increase at the Stirling engines "sink" in numerous experiments
Instead, like the bird, there is actually a temperature decrease without any "transfer" of "heat" from one location to another. Rather than being "removed", the heat is transformed.
If "heat" is leaving the birds head as heat, then that heat should appear as a temperature increase outside the birds head. But there is no "heat" leaving the birds head or being "rejected".
The cooling is a result of something other than heat transfer.
At the interface between liquid water on the felt on the birds head and the surrounding air you have individual water molecules breaking bonds with other water molecules which takes energy. That energy consumption results in a drop in temperature.
Are those escaping water molecules "hotter"?
Really, there is no such thing as heat. Only different forms of motion
In a Stirling engine the random molecular gas motion is persuaded to oscillate in a rhythmic manner that has an impact on the piston, transferring energy to the piston setting it in motion.
This cyclical transfer of energy reduces the energy of the gas resulting in a drop in temperature and a drop in pressure below atmosphere so the piston can return and complete the cycle, then heat is again added at the start of another cycle.
No "heat" is "rejected" or "removed", unless you define "removed" as transformed.
The energy of the microscopic molecular motion of the gas is transfered to produce the motion of the engine.
The engine could turn a generator that produces electricity that goes through wires and eventually reaches a resistance heating appliance so that the "removed" so-called "heat" then re-emerges, but again, such a remote re-emergence, if you want to look at it that way, has no effect on the local cyclic operation of the engine.
The electrical load would slow it down presumably, but the result is cooling of the working fluid by an energy transfer or transformation, not "heat" transfer to a "sink".
You can view it, or define it however you like to preserve your precious "Carnot theorem" I don't really care
What concerns me is; if I have a Stirling engine "running on ice", does the heat flow through the engine into the ice or can it be transformed so that the energy or "heat" is released or re-emerges at some remote location?
If the heat, derived from the ambient surroundings comes out of a space heater somewhere, but does not directly influence the ice the engine is running on then Tesla's proposed ambient heat powered engine appears doable.
The bird is an example
The heat "removed" may reappear when the evaporating water condenses somewhere. So what?
The bird still runs.