Fool wrote: ↑Tue Jul 25, 2023 8:29 pm
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I prefer to think about pressure. During expansion: 100% of the heat, entering the working gas, results in a pressure that does a work output of 100%.
This is generally consistent with the published theory and information. 100% conversion to work during a process is not only possible but the consequence of the first law, conservation of energy. So it is supposedly only on the return stroke where the consequences of the Carnot limit come into play in a cyclic process.
Compression to complete the cycle requires 80% of that gained work if, and only if, the gas is cooled by a 20% temperature difference accomplished by heat rejection.
If the gas is not cooled, compression (Adiabatically) requires 100% of the work and zero heat is converted to cyclic useable work output. If cooled more it requires less. Rejecting heat reduces the loss of work. Not rejecting any heat costs all the work for compression.
It costs 80% or more to compress the gas thus completing the cycle. 80% is only for the best path. One needs to look at the path (PV and TS diagram) of the entire cycle to understand the Carnot limit, not just a single process.
In reading Kelvin previously, (the complete commentary on Carnot's (caloric based) theories, it seems clear that the PV diagram he introduced (not sure if it's original with Kelvin but anyway) originates from or is based on the concept (caloric theory) that work is generated by transferring ALL the heat through the engine from source to sink. In that case there is no accounting for heat converted to work in a PV diagram. Work is just a byproduct of heat transfer.
This appears to be more or less the case in your focus on pressure.
Heat is introduced, increasing pressure
You stated: "During expansion: 100% of the heat, entering the working gas, results in a pressure that does a work output of 100%"
Being cautious at this point, if the above statement is true, the conclusions that followed that are false:
In a Stirling engine the working fluid is contained in a hermetically sealed chamber. (Mostly or practically, some leaks in a model engine are possible, but can be ignored for the current purpose)
First heat is added. Next the pressure of the working gas in the chamber increases. Eventually the inertia of the engine, piston, flywheel, crank and load etc. is overcome and the piston is driven out and as you say: "During expansion: 100% of the heat, entering the working gas, results in a pressure that does a work output of 100%"
Now thinking about this logically based on known principles of rapid gas expansion, at the end of the expansion process is there any of this increased pressure remaining?
Conservation of energy would seem to suggest that if the heat originally supplied, resulting in a pressure that "does a work output of 100%" we now have an engine in motion and the heat that caused the pressure is gone.
Newtons 1st law of motion states that an object in motion remains in motion unless acted on by some other force.
Is it logical to believe that after the added heat results in a "work output of 100%" the resulting increase in pressure that resulted from that heat addition remains??????
The increase in pressure was a consequence of heat input which by the end of the expansion stroke has been 100% converted from heat into the mechanical motion of the engine.
The heat that created the increase in pressure is now gone, converted, so it can be logically assumed that the heat that caused the pressure being gone, the pressure that resulted from the presence of that heat should be gone as well
In other words, the conversion of the heat 100% to mechanical motion means there is no longer any increased pressure to prevent the piston from returning. Infact, due to the fact that the chamber is sealed and the piston has changed position the state of the working fluid can now be considered a vacuum. This vacuum results in the piston being sucked back to its starting position, or preferably we can say it is pushed back by atmospheric pressure.
Or please explain how the pressure that set the engine in motion can continue to exist once the cause of that pressure, the added heat, has been converted to mechanical motion.
Your statement: "If the gas is not cooled, compression (Adiabatically) requires 100% of the work and zero heat is converted to cyclic useable work output." overlooks the several facts just pointed out.
The working fluid is in a sealed chamber. If the expansion work results in 100% conversion of the heat added at the start of the cycle to work (mechanical motion of the engine) the heat, which is the causative force behind the pressure is gone from the working fluid so the pressure which was an effect of the added heat, (now gone, having been converted to work), is also gone and the gas returns to its original state and so, of necessity will contract.
This is the observable reality that can be seen and measured and plotted in real time.
https://youtu.be/SHyke4hUNOs
The scenario you describe, where the heat is converted to work, but somehow the pressure caused by the heat remains to fight against the continued motion of the engine through the compression stroke is a violation of conservation of energy.