Sorry this took so long. I had to find my 2014 Lap top. Chisel off many layers of rock, fossils and dinosaur bones. Man they pile up fast. Dust it off, Charge it up. Start up and stoke the steam boiler. Allow time for it to come up to temperature and pressure. Boot strap load the operating system. Find the old files. Start the spread sheet and word processer. Okay so some of that is artistic license, storytelling. LOL
I promised to comment on this thread with some mathematics, so here it goes. Some of this is corrections, minor, and some is branching out to a more detailed pondering, some is just grammar and convention.
1 Joule = 0.737562 Ft-Lbs (Not Ft/Lbs)
Round able to 0.74
1 Joule is 1 Newton of force used to move an object 1 meter of distance. AKA: Energy.
Torque is in Lbs-Ft (Pounds times Feet), often colloquially spoken: Foot Pounds. Not the same as Energy. Torque is Newtons, or Pounds times a perpendicular distance, length of lever arm, Meter or Foot, and can be applied to something without motion. Again, not Energy, Force times a moved Distance. Yes, Force times lever arm no motion necessary. AKA twisting force.
There are two Heat Capacities, Cv and Cp, at STP, using SI (System International), Meters, Kilograms, Seconds, (I convert everything to SI.) :
Cv = 718 to J/kg Constant Volume Heat addition.
Cp = 1005 J/kg Constant Pressure Heat addition.
They change very little over the pressures and temperatures given for this example.
Displacer Diameter = 0.3048 m = 1 foot x 12 x 2.54 / 100
Cylinder effective length = 0.0127 = (1 inch - 0.5 inch) x 2.54 / 100
Effective volume = 0.000926667 m^3 = 56.54866776 in^3 (Close enough to yours.)
Density of air = 1.225 kg/m^3 at STP
Mass of air = 0.001135167 kg = Density x Volume = 0.000926667 x 1.225
Moles of air per kilogram = 0.0289 Moles/kg
Moles of air = 0.039279122 = 0.0289 x 0.001135167
T1 STP = 293.15 K = 20 C
Given starting temperature.
T2 = 373.15 K = 100 C
Given ending temperature T hot.
Delta-T = 80 K and C = T2 - T1
P1 = STP = C 101325 Pa (Pascals) (N/m^2) = 14.6959494 psi
The given starting, Standard Temperature and Pressure, STP.
Calculations:
P2 = 128976.373 Pa = P1 x T2 / T1 = 18.70644216 psi
Delta pressure = 27651.37302 Pa = 4.010492758 psi
This is at V1.
Heat added to get to T2, P2:
This would be Heat Capacity times Delta T times mass. Since there are two Heat Capacities Cv and Cp, the correct one must be justified. Since the volume of this is not changing and the pressure is, we choose Cv for constant volume (isochoric) heat addition.
Qh = 65.2039713 Joules = 718 x 80 x 0.001135167
That number is different from yours because you used Cp. If I use Cp I get 91.26 Joules. That is different from your 96 Joules because of rounding differences. So we are comparable here. Cv is smaller than Cp because temperature rises with increased pressure. Since Cv must account for increased temperature from pressure increases, it takes less heat energy/Joules, than for Cp, to get to the same temperature.
Now to calculate the PV factors, sometimes called Pressure Volume Energy. It assumes a Delta-V of total V, or Vtotal, and zero pressure change, also called constant pressure process. In a real adiabatic expansion the pressure will drop, but we are just calculating it here. It would be easier to understand seeing a graph of this.
P1V1 = 93.894497 Joules = 101325 Pa x 0.000926667 m^3
P2V1 = 119.5181 Joules = 128976.373 Pa x 0.000926667 M^3
Constant volume, increased pressure from temperature.
PV energy difference from added heat,
P2V1 – P1V1 = 25.623605 Joules
PV heat change divided by heat in:
25.623605 / 65.2039713 = 0.392976139 or about 39%
Carnot for this is:
80 / 373.15 = 0.214390996 or about 21%
At this point it will be noted that the change in PV energy doesn’t equal the Heat added. The percent loss isn’t the same as expected by the Carnot Theorem either. However, the Carnot theorem is for a complete cycle, not a single stroke or for a PV energy equivalence. However a constant volume and pressure CALCULATION also has zero energy out, so the overall “energy out” efficiency of this process is also ZERO.
I think the opening post confused total energy at T2 with “Delta Energy” from Delta Pressure 4 psi, or change in PV energy factor. And confusion of Cv for Cp. It also didn’t recognize that real Energy/Work out was zero. Efficiency is real work out over real work in, not Energy Stored.
This concludes the corrections to the opening post.
I would like to explore a little further and look at some maximum work out from a half cycle, or single expansion stroke. The actual real work available will be less, than the following, because we will be ignoring mechanical, and other, losses.
Let us try expanding, adiabatically with work (isentropically), until the volume P3 = P1, or it is back down to the atmospheric/beginning pressure.
Expanding back down to atmospheric will give the maximum available work out of the working gas for an isochoric process, because at the point where P3 equals P1, the piston has reached its maximum velocity and kinetic energy. Expanding any further will require pulling a vacuum with associated work input and a decrease in piston velocity, i.e., less maximum energy to output as work. I’ve use the equations from the Wikipedia page on Adiabatic Processes for the following:
https://en.m.wikipedia.org/wiki/Adiabatic_process
Single stroke P2 back to P1 = P3:
Gamma = Cp/Cv = 1005 / 718 = 1.399721448
Alpha = 1/(Cp/Cv-1) 1/(1005/718-1) = 2.50174216
A good check of Gama at this point is that:
Gama also = (5+2)/5 = (Degrees of Freedom + 2) / Degrees of freedom
Degrees of freedom = 5 for an Ideal diatomic gas like oxygen and nitrogen.
W = 20.29956414 Joules = -Alpha x n x R x T2 x
{(P3/P2)^([Gama-1]/Gama) – 1}
Where:
W = Work
n = number of moles = 0.039279122
R = Gas constant for air = 8.314
W = -2.50174216 x 0.039279122 x 8.314 x 373.15 x
((101325/128976.373)^((1.399721448-1)/1.399721448) -1)
W = 20.29956414 Joules
Comparing the isentropic work with the Carnot efficiency:
20.29956414/65.2039713 = 0.311324046 or about 31%.
That is still not as low as the Carnot efficiency of about 21.4%
At this point it should be noted that the “perfect” efficiency of the one half cycle Adiabatic/Isentropic process is less than 100%, yet it isn’t as low as the Carnot Efficiency. That is because the Carnot efficiency theorem needs a return stroke to complete the cycle. The return stroke if Isentropic will need 20.29956414 Joules of energy input of work and will get back to P2 and V1 and T2. Not P1, V1 and T1. This leaves zero energy for output as work. However, 65.2 Joules of heat would need to be rejected to reduce the pressure and temperature back to initial conditions. A graph would also help to visualize this.
V3 = V1 x (P1/P2)^(-1/Gamma) = 0.000926667 x
(101325/128976.373)^(-1/1.399721448)
V3 = 0.001101009 m^3
This is larger than V1meaning it has expanded, and is now back to P1.
T3 is determined by Pressure ratio times T2
T3 = T2 x (P1/P2)^([Gama-1]/Gama) = 373.15 x
(0.000926667 / 128976.373)^([ 1.399721448-1]/ 1.399721448)
T3 = 348.3030909 K
Note: This is significantly lower than T2 but not back to T1. It can be reflected by the need for there to be a higher temperature than T1 to support the larger volume of V3.
It also means to return to T1, at this volume, heat must be rejected, or stored in the regenerator. The Carnot process can also be used by putting in work, for isentropic adiabatic expansion/vacuum, to create a lower pressure than P1/atmospheric, and a lower temperature back down to T1. The work will be returned on the compression stroke because the internal pressure is lower than the external atmosphere pressure. AKA adiabatic bounce, work in equals work out, total zero for a complete cycle.
It will buy nothing unless the return stroke is done at T1, constant temperature heat rejection. Then the return stroke will require less than the extra expansion work delivered. And the adiabatic, “Carnot” compression back to T1 and P1 initial conditions will require input of work further slowing the piston.
My conclusion from this exercise is that the Carnot Theorem is verified, or at least not disproven.
Disclaimer: I’ve checked and rechecked the above calculations and have made every attempt to assure their correctness. If errors are found, please check for them, and I’m informed, if possible I’ll repost a correction. Thanks for allowing my posting here. My apologies for being so long, tedious, and boring. I intend it to be useful and informative.